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2 edition of The Synthesis of aminophosphonic acid derivatives and related compounds. found in the catalog.

The Synthesis of aminophosphonic acid derivatives and related compounds.

Donovan St. Claire Green

The Synthesis of aminophosphonic acid derivatives and related compounds.

by Donovan St. Claire Green

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  • 10 Currently reading

Published .
Written in English


The Physical Object
Pagination370 leaves
Number of Pages370
ID Numbers
Open LibraryOL13766470M

Stereoselective Synthesis of α-Aminophosphonic Acids Analogs of the 20 Proteinogenic α-Amino Acids He has authored > scientific publications and holds 23 patents. He has edited 20 books and chapters (ACS book series, John Wiley & Sons, Springer, Elsevier,CRC Press, Taylor & Francis), and has also delivered more than 60 invited lectures. The synthesis of aminophosphonic acid derivatives & related compounds 1-Aminoalkanephosphonic acids and their derivatives, have long been claimed to be compounds with a wide variety of application. Numerous examples exist where they have been described as: complex-forming agents with sequestrating properties, extractants, wetting agents Author: Donovan St Claire Green. 1. Introduction. α-Aminophosphonic acids (APAs) and their derivatives are an important class of compounds that exhibited intriguing biological activities [1–10].A number of potent antibiotics, herbicides, antitumor agents [11–15] and enzyme inhibitors [] are APAs or their er, these compounds have been evaluated as inhibitors of matrix metalloproteinases MMP-1, MMP-2, MMP Cited by: @article{osti_, title = {SYNTHESIS AND PHYSICAL PROPERTIES OF A NOVEL AMINOPHOSPHONIC ACID AS AN EXTRACTING AGENT FOR METALS.}, author = {Jagodic, V and Herak, M J}, abstractNote = {}, doi = {/(70)}, journal = {J. Inorg. Nucl.

ISBN: OCLC Number: Description: xxv, pages: illustrations ; 24 cm: Contents: Naturally Occurring Aminophosphonic and Aminophosphinic Acids (P. Mastalerz & P. Kafarski); Synthesis of -Aminoalkanephosphinic Acids (P. Kafarski & J. Zo); Synthesis of Aminoalkanephosphonic and Aminoalkanephosphinic Acids with the .   APPLIED ORGANOMETALLIC CHEMISTRY Appl. Organometal. Chem. 14, – () Book reviews Aminophosphonic and aminophosphinic acids: chemistry and biological activity Valery P. Kukhar and Harry R. Hudson (eds) John Wiley & Sons Ltd, Chichester, xxv pages. £ ISBN This is a substantial and authoritative work that will be of spectra and . The Abramov reaction is the related conversions of trialkyl to α-hydroxy phosphonates by the addition to carbonyl compounds. In terms of mechanism, the reaction involves attack of the nucleophilic phosphorus atom on the carbonyl carbon. It was named after the Russian chemist Vasilii Semenovich Abramov (–) in Figures from the book. All the diagrams from the book available to download in electronic format. Solutions to end-of-chapter problems. Solutions for all end-of-chapter problems from the book. Examples of organic synthesis reactions. Examples of organic synthesis reactions related to topics covered in the book. Additional problems and solutions.

The carboxyl group (abbreviated -CO 2 H or -COOH) is one of the most widely occurring functional groups in chemistry as well as biochemistry. The carboxyl group of a large family of related compounds called Acyl compounds or Carboxylic Acid Derivatives.. All the reactions and compounds covered in this section will yield Carboxylic Acids on hydrolysis, and thus are known as Carboxylic Acid. This is a thoroughly updated edition of one of the best selling titles in the Oxford Chemistry Primer series. John Jones provides an excellent, easy to read introduction to amino acid and peptide synthesis aimed at second and final year by:   This is the second of five books in the Amino Acids, Peptides and Proteins in Organic Synthesis series. Closing a gap in the literature, this is the only series to cover this important topic in organic and biochemistry. Drawing upon the combined expertise of the international whos who in amino acid research, these volumes represent a real benchmark for amino acid chemistry, providing a Author: Andrew B. Hughes. The synthesis of highly substituted chiral hydantoins from simple dipeptides proceeded through the dual activation of an amide and a tert-butyloxycarbonyl (Boc) protecting group by Tf 2 O-pyridine under mild conditions in a single step. This method was successfully applied in the preparation of various biologically active compounds, including.


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The Synthesis of aminophosphonic acid derivatives and related compounds. by Donovan St. Claire Green Download PDF EPUB FB2

Related Books SoS C-1 Building Blocks in Organic Synthesis SoS Multicomponent Reactions Simple and Improved Preparation of α-Aminophosphonic Acid Derivatives, Studies on Isocyanides and Related Compounds: A Novel Synthesis of The Synthesis of aminophosphonic acid derivatives and related compounds.

book via Ugi Reaction. In recent years, phosphonic acids and their derivatives have received increasing attention as analogues of a series of naturally occurring phosphates and as “bio-isosteric phosphorus analogues” of aminoacids.

Unlike a phosphate group, the phosphonate moiety is not readily hydrolyzed, in a biological environment, by the enzymes involved in the phosphate cleavage. Related Books SoS C-1 Building Blocks in Organic Synthesis The synthesis of a new series of arylhydroxymethylphosphinic acid derivatives is described.

The protected compounds were prepared by a palladium(0) catalysed arylation of ethyl benzyl­oxymethylphosphinate with aryl halides. In Aminophosphonic and Aminophosphinic Acids Cited by: Keywords:Aminophosphonic acids, Aminophosphonates, Synthesis, Asymmetric synthesis, Biological activity.

Abstract: In The Synthesis of aminophosphonic acid derivatives and related compounds. book years, phosphonic acids and their derivatives have received increasing attention as analogues of a series of naturally occurring phosphates and as “bio-isosteric phosphorus analogues” of aminoacids.

Unlike a phosphate group, the phosphonate moiety is not Cited by: Asymmetric Synthesis of Aminophosphonic Acids and Trifluoromethylated Derivatives Thereof.

Phosphorus, Sulfur, and Silicon and the Related Elements(), DOI: / Eusebio Juaristi, José Luis León-Romo, Adelfo Reyes, Jaime by: Related Books SoS C-1 Building Blocks in Organic Synthesis Facile Synthesis of Pyridine Derivatives Full Text Aminophosphonic Acids; XVI 1.

A New and Facile Synthesis of Phosphinothricine and 2-Aminophosphonobutanoic Acid Full Text PDF ( kb)   Reduction with sodium cyanborohydride in the presence of zinc chloride and the catalytic hydrogenation of β-enaminophosphonates gives β-aminophosphonates.

β-Enaminophosphonates are also used as intermediates for the regioselective synthesis of fluoroalkyl-substituted by: Page Issue in Honor of Prof. Heinz Heimgartner ARKIVOC (vi) Thioureidoalkylphosphonates in the synthesis of 1-aminoalkylphosphonic acids.

The Ptc-aminophosphonate method Marcin H. Kudzin,a Zbigniew H. Kudzin, b* and Jozef Drabowiczc,d aTextile Research Institute, Brzezinska 5/15, LodzPoland bFaculty of Chemistry, University of Lodz. The book presents detailed discussions of the most important methods for the synthesis of ß-amino acids.

In most cases, the lead chemist who originally developed a method provides an authoritative description of it. In addition, Enantioselective Synthesis of ß-Amino Acids, Second Edition.

Chemistry and Application of H-Phosphonates is an excellent source for those planning the synthesis of new phosphorus-containing compounds and in particular derivatives containing a phosphonate, phosphoramide or phosphonic acid diester group.

The rich chemistry, low cost and easy availability of diesters of H-phosphonic acid makes them an excellent choice as synthone in a number of practically. The first representatives of enantiomerically pure (S) and (R) α-aminophosphonates and aminophosphonic acids bearing HCF 2 CF 2, C 3 F 7 or CF 2 Cl group in α-position were prepared.

The synthesis of novel chiral building block, (R)-N-tert-butylsulfinylimine Cited by: 1. Recent Advances in the Synthesis of Fluorinated Aminophosphonates and Aminophosphonic Acids Article in RSC Advances 44(33) August with Reads How we measure 'reads'.

Most of the described methods for the synthesis of aminophosphonic acids use carbonyl compounds, such as aldehydes, ketones, or carboxylic acids as starting compounds. Modern Radical Methods and their Strategic Applications in Synthesis Bürgenstock Special Section – Future Stars in Organic Chemistry Modern Strategies for Borylation in SynthesisCited by:   Aminophosphonic acids are an important group of medicinal compounds, and their synthesis has been a focus of considerable attention in synthetic organic chemistry as well as medicinal chemistry.

Although the phosphonic and carboxylic acid groups differ considerably with respect to shape, size, and acidity, α-aminophosphonic acids are considered to be structural analogues of the Cited by: Considering the high value of these non-coded compounds in connection with our current research interest in the synthesis of novel conformationally restricted α-aminophosphonic acids [26,27,28,41,42,43], we now report herein the practical and efficient synthesis of α-aminophosphonic acids incorporating 1,2,3,4-tetrahydroquinoline 4, and 1,2,3,4-tetrahydroisoquinoline rings 5 and 6, Cited by: 7.

Aminophosphonates and aminophosphonic acids with tetrasubstituted stereogenic center: diastereoselective synthesis from cyclic ketimines† Jakub Iwanejko, a Anna Brol, a Bartłomiej M.

Szyja, b Marek Daszkiewicz, c Elżbieta Wojaczyńska * a and Tomasz K. Olszewski * aAuthor: Jakub Iwanejko, Anna Brol, Bartłomiej M.

Szyja, Marek Daszkiewicz, Elżbieta Wojaczyńska, Tomasz K. AMINOPHOSPHONIC ACIDS AND RELATED COMPOUNDS. This is my library of compounds resulting from the last 11 years of studies.

It contains mostly phosphorous compounds, such as aminophosphonic, aminophosphinic, hydrazinophosphonic, diaminophosphonic, aminocarboxyphosphonic, aminodiphosphonic, iminodiphosphonic and N-alkyl-substituted aminophosphonic acids, their numerous derivatives. α-Amino-C-phosphinic acids and derivatives are an important group of compounds of synthetic and medicinal interest and particular attention has been dedicated to their stereoselective synthesis in recent years.

Among these, phosphinic pseudopeptides have acquired pharmacological importance in influencing physiologic and pathologic processes, primarily acting as inhibitors for proteolytic Cited by: 9.

Keywords: Cyclic α-aminophosphonic acids, Kabachnik-Fields, Pudovik reactions Table of Contents 1. Introduction 2. Type A: Cyclic α-Aminophosphonic Acid Derivatives Bearing an Exocyclic Amino Group (Heterocycles containing the phosphorus as a ring heteroatom) Curtius rearrangement strategy on phosphorus heterocycles.

This text presents all aspects of the chemistry and biological activity of aminophosphinic and pdf acids and their pdf including esters and peptides, with emphasis on contemporary research in agrochemical and biomedical applications.

The book includes structural and spectroscopic data, covers research in biological activity with special reference to protease inhibition and possible clinical applications, and explores the use of aminophosphinic and aminophosphonic.Aminophosphonates are organophosphorus compounds with the formula (RO) 2 Download pdf 2 NR" compounds are structural analogues of amino acids in which a carboxylic moiety is replaced by phosphonic acid or related groups.

Acting as antagonists of amino acids, they inhibit enzymes involved in amino acid metabolism and thus affect the physiological activity of the cell. The chiral Schiff bases ebook from esters of glycine and chiral carbonyl compounds are one ebook the most popular approaches for the asymmetric synthesis of α-amino acids.

In a similar way, the chiral Schiff bases prepared from phosphoglycine have been also used in the asymmetric synthesis of α-aminophosphonic by: